Currently R7RS is silent on what truncate, floor, ceiling, and round do when the argument is +inf.0, -inf.0, or +nan.0. R6RS has them return the argument, which seems reasonable.
I tested (round (* 1.0e200 1.0e200)) on my usual suite of Schemes. Racket, Gauche, Chicken (with and without the numbers egg), Bigloo, Guile, Kawa, Chibi, Chez, SCM, Ikarus/Vicare, Larceny, Ypsilon, Mosh, IronScheme, NexJ, STklos, KSi, Shoe, BDC, Rep, Schemik, Elk, Spark all return the argument.
MIT, Gambit, Scheme48/scsh, SISC, Scheme 9, Scheme 7, signal errors.
SigScheme, TinyScheme, Dream, UMB don't work for one or another reason.
Oaklisp and Owl Lisp don't do flonums.
XLisp only has fixnums and flonums, and returns the largest or smallest fixnum as the case may be.
RScheme returns a variety of slightly strange values: (round +inf.0), for example, is 0, but (round -inf.0) is -inf.0.
WG1 decided that these functions return these arguments unchanged.